Direct validation of the restriction of intramolecular rotation hypothesis via the synthesis of novel ortho-methyl substituted tetraphenylethenes and their application in cell imaging

Direct validation of the restriction of intramolecular rotation hypothesis via the synthesis of novel ortho-methyl substituted tetraphenylethenes and their application in cell imaging

We demonstrate a novel synthetic approach to ortho-methyl substituted tetraphenylethene materials, which can be utilised for directly validating the restriction of intramolecular rotation hypothesis as the basic mechanism of aggregation-induced emission phenomenon and cell imaging.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2014-10, Vol.50 (81), p.12058-12060
Hauptverfasser: Zhang, Guo-Feng, Chen, Ze-Qiang, Aldred, Matthew P, Hu, Zhe, Chen, Tao, Huang, Zhenli, Meng, Xianggao, Zhu, Ming-Qiang
Format: Artikel
Sprache:eng
Schlagworte:
Crystallography, X-Ray
Ethylenes - chemical synthesis
Ethylenes - chemistry
Ethylenes - metabolism
Fluorescent Dyes - chemistry
Fluorescent Dyes - metabolism
HeLa Cells
Humans
Microscopy, Confocal
Molecular Conformation
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Beschreibung
Zusammenfassung:We demonstrate a novel synthetic approach to ortho-methyl substituted tetraphenylethene materials, which can be utilised for directly validating the restriction of intramolecular rotation hypothesis as the basic mechanism of aggregation-induced emission phenomenon and cell imaging.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc04241g