Electricity Resonance-Induced Fast Transport of Water through Nanochannels

We performed molecular dynamics simulations to study water permeation through a single-walled carbon nanotube with electrical interference. It was found that the water net flux across the nanochannel is greatly affected by the external electrical interference, with the maximal net flux occurred at a...

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Veröffentlicht in:Nano letters 2014-09, Vol.14 (9), p.4931-4936
Hauptverfasser: Kou, Jianlong, Lu, Hangjun, Wu, Fengmin, Fan, Jintu, Yao, Jun
Format: Artikel
Sprache:eng
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Zusammenfassung:We performed molecular dynamics simulations to study water permeation through a single-walled carbon nanotube with electrical interference. It was found that the water net flux across the nanochannel is greatly affected by the external electrical interference, with the maximal net flux occurred at an electrical interference frequency of 16670 GHz being about nine times as high as the net flux at the low or high frequency range of (80 000 GHz). The above phenomena can be attributed to the breakage of hydrogen bonds as the electrical interference frequency approaches to the inherent resonant frequency of hydrogen bonds. The new mechanism of regulating water flux across nanochannels revealed in this study provides an insight into the water transportation through biological water channels and has tremendous potential in the design of high-flux nanofluidic systems.
ISSN:1530-6984
1530-6992
DOI:10.1021/nl500664y