Energy and Chemicals from the Selective Electrooxidation of Renewable Diols by Organometallic Fuel Cells
Organometallic fuel cells catalyze the selective electrooxidation of renewable diols, simultaneously providing high power densities and chemicals of industrial importance. It is shown that the unique organometallic complex [Rh(OTf)(trop2NH)(PPh3)] employed as molecular active site in an anode of an...
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| Veröffentlicht in: | ChemSusChem 2014-09, Vol.7 (9), p.2432-2435 |
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| creator | Bellini, Marco Bevilacqua, Manuela Filippi, Jonathan Lavacchi, Alessandro Marchionni, Andrea Miller, Hamish A. Oberhauser, Werner Vizza, Francesco Annen, Samuel P. Grützmacher, H. |
| description | Organometallic fuel cells catalyze the selective electrooxidation of renewable diols, simultaneously providing high power densities and chemicals of industrial importance. It is shown that the unique organometallic complex [Rh(OTf)(trop2NH)(PPh3)] employed as molecular active site in an anode of an OMFC selectively oxidizes a number of renewable diols, such as ethylene glycol , 1,2‐propanediol (1,2‐P), 1,3‐propanediol (1,3‐P), and 1,4‐butanediol (1,4‐B) to their corresponding mono‐carboxylates. The electrochemical performance of this molecular catalyst is discussed, with the aim to achieve cogeneration of electricity and valuable chemicals in a highly selective electrooxidation from diol precursors.
Cellmates: Organometallic fuel cells (OMFC) catalyze the selective electrooxidation of renewable diols such as ethylene glycol, 1,2‐propanediol, 1,3‐propanediol, and 1,4‐butanediol, simultaneously providing high power densities and chemicals of industrial importance. [Rh(OTf)(trop2NH)(PPh3)], an organometallic complex, is employed as molecular active site in an anode of an OMFC and its electrochemical performance is evaluated. |
| doi_str_mv | 10.1002/cssc.201402316 |
| format | Article |
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Cellmates: Organometallic fuel cells (OMFC) catalyze the selective electrooxidation of renewable diols such as ethylene glycol, 1,2‐propanediol, 1,3‐propanediol, and 1,4‐butanediol, simultaneously providing high power densities and chemicals of industrial importance. [Rh(OTf)(trop2NH)(PPh3)], an organometallic complex, is employed as molecular active site in an anode of an OMFC and its electrochemical performance is evaluated.</description><identifier>ISSN: 1864-5631</identifier><identifier>EISSN: 1864-564X</identifier><identifier>DOI: 10.1002/cssc.201402316</identifier><identifier>PMID: 25082272</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Bioelectric Energy Sources ; carboxylates ; Electrochemistry ; energy conversion ; Fuel cells ; Glycols - chemistry ; Organometallic Compounds - chemistry ; organometallic fuel cell ; oxidation ; Oxidation-Reduction ; renewable alcohols ; rhodium ; Substrate Specificity</subject><ispartof>ChemSusChem, 2014-09, Vol.7 (9), p.2432-2435</ispartof><rights>2014 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><rights>2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c5186-a501bd4dcd4fe8e6ea91c2df154f60c769696b940b458daa1b4c2b835ce8fc9c3</citedby><cites>FETCH-LOGICAL-c5186-a501bd4dcd4fe8e6ea91c2df154f60c769696b940b458daa1b4c2b835ce8fc9c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fcssc.201402316$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fcssc.201402316$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/25082272$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Bellini, Marco</creatorcontrib><creatorcontrib>Bevilacqua, Manuela</creatorcontrib><creatorcontrib>Filippi, Jonathan</creatorcontrib><creatorcontrib>Lavacchi, Alessandro</creatorcontrib><creatorcontrib>Marchionni, Andrea</creatorcontrib><creatorcontrib>Miller, Hamish A.</creatorcontrib><creatorcontrib>Oberhauser, Werner</creatorcontrib><creatorcontrib>Vizza, Francesco</creatorcontrib><creatorcontrib>Annen, Samuel P.</creatorcontrib><creatorcontrib>Grützmacher, H.</creatorcontrib><title>Energy and Chemicals from the Selective Electrooxidation of Renewable Diols by Organometallic Fuel Cells</title><title>ChemSusChem</title><addtitle>ChemSusChem</addtitle><description>Organometallic fuel cells catalyze the selective electrooxidation of renewable diols, simultaneously providing high power densities and chemicals of industrial importance. It is shown that the unique organometallic complex [Rh(OTf)(trop2NH)(PPh3)] employed as molecular active site in an anode of an OMFC selectively oxidizes a number of renewable diols, such as ethylene glycol , 1,2‐propanediol (1,2‐P), 1,3‐propanediol (1,3‐P), and 1,4‐butanediol (1,4‐B) to their corresponding mono‐carboxylates. The electrochemical performance of this molecular catalyst is discussed, with the aim to achieve cogeneration of electricity and valuable chemicals in a highly selective electrooxidation from diol precursors.
Cellmates: Organometallic fuel cells (OMFC) catalyze the selective electrooxidation of renewable diols such as ethylene glycol, 1,2‐propanediol, 1,3‐propanediol, and 1,4‐butanediol, simultaneously providing high power densities and chemicals of industrial importance. [Rh(OTf)(trop2NH)(PPh3)], an organometallic complex, is employed as molecular active site in an anode of an OMFC and its electrochemical performance is evaluated.</description><subject>Bioelectric Energy Sources</subject><subject>carboxylates</subject><subject>Electrochemistry</subject><subject>energy conversion</subject><subject>Fuel cells</subject><subject>Glycols - chemistry</subject><subject>Organometallic Compounds - chemistry</subject><subject>organometallic fuel cell</subject><subject>oxidation</subject><subject>Oxidation-Reduction</subject><subject>renewable alcohols</subject><subject>rhodium</subject><subject>Substrate Specificity</subject><issn>1864-5631</issn><issn>1864-564X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkc1P3DAQxS3Uiq_22mNlqZdesrUd20mOkC4fEgKJpSrqxXKcCWvqxNROCvvf49XCCvVSzWHm8HtPT_MQ-kTJjBLCvpkYzYwRygnLqdxB-7SUPBOS377b3jndQwcx3hMiSSXlLtpjgpSMFWwfLecDhLsV1kOL6yX01mgXcRd8j8cl4AU4MKP9C3i-PoL3T7bVo_UD9h2-hgEedeMAf7c-yZoVvgp3evA9jNo5a_DJBA7X4Fz8gN53yRo-vuxD9ONkflOfZRdXp-f10UVmRIqbaUFo0_LWtLyDEiToihrWdlTwThJTyCpNU3HScFG2WtOGG9aUuTBQdqYy-SH6uvF9CP7PBHFUvY0mJdAD-CkqKiQlOROUJ_TLP-i9n8KQ0q0pQigtqiJRsw1lgo8xQKcegu11WClK1LoDte5AbTtIgs8vtlPTQ7vFX5-egGoDPFoHq__YqXqxqN-aZxutjSM8bbU6_FayyAuhfl6eKnIpbo7Z7S91nT8DZFai8Q</recordid><startdate>201409</startdate><enddate>201409</enddate><creator>Bellini, Marco</creator><creator>Bevilacqua, Manuela</creator><creator>Filippi, Jonathan</creator><creator>Lavacchi, Alessandro</creator><creator>Marchionni, Andrea</creator><creator>Miller, Hamish A.</creator><creator>Oberhauser, Werner</creator><creator>Vizza, Francesco</creator><creator>Annen, Samuel P.</creator><creator>Grützmacher, H.</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>K9.</scope><scope>7X8</scope></search><sort><creationdate>201409</creationdate><title>Energy and Chemicals from the Selective Electrooxidation of Renewable Diols by Organometallic Fuel Cells</title><author>Bellini, Marco ; Bevilacqua, Manuela ; Filippi, Jonathan ; Lavacchi, Alessandro ; Marchionni, Andrea ; Miller, Hamish A. ; Oberhauser, Werner ; Vizza, Francesco ; Annen, Samuel P. ; Grützmacher, H.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5186-a501bd4dcd4fe8e6ea91c2df154f60c769696b940b458daa1b4c2b835ce8fc9c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Bioelectric Energy Sources</topic><topic>carboxylates</topic><topic>Electrochemistry</topic><topic>energy conversion</topic><topic>Fuel cells</topic><topic>Glycols - chemistry</topic><topic>Organometallic Compounds - chemistry</topic><topic>organometallic fuel cell</topic><topic>oxidation</topic><topic>Oxidation-Reduction</topic><topic>renewable alcohols</topic><topic>rhodium</topic><topic>Substrate Specificity</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bellini, Marco</creatorcontrib><creatorcontrib>Bevilacqua, Manuela</creatorcontrib><creatorcontrib>Filippi, Jonathan</creatorcontrib><creatorcontrib>Lavacchi, Alessandro</creatorcontrib><creatorcontrib>Marchionni, Andrea</creatorcontrib><creatorcontrib>Miller, Hamish A.</creatorcontrib><creatorcontrib>Oberhauser, Werner</creatorcontrib><creatorcontrib>Vizza, Francesco</creatorcontrib><creatorcontrib>Annen, Samuel P.</creatorcontrib><creatorcontrib>Grützmacher, H.</creatorcontrib><collection>Istex</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>ChemSusChem</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bellini, Marco</au><au>Bevilacqua, Manuela</au><au>Filippi, Jonathan</au><au>Lavacchi, Alessandro</au><au>Marchionni, Andrea</au><au>Miller, Hamish A.</au><au>Oberhauser, Werner</au><au>Vizza, Francesco</au><au>Annen, Samuel P.</au><au>Grützmacher, H.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Energy and Chemicals from the Selective Electrooxidation of Renewable Diols by Organometallic Fuel Cells</atitle><jtitle>ChemSusChem</jtitle><addtitle>ChemSusChem</addtitle><date>2014-09</date><risdate>2014</risdate><volume>7</volume><issue>9</issue><spage>2432</spage><epage>2435</epage><pages>2432-2435</pages><issn>1864-5631</issn><eissn>1864-564X</eissn><abstract>Organometallic fuel cells catalyze the selective electrooxidation of renewable diols, simultaneously providing high power densities and chemicals of industrial importance. It is shown that the unique organometallic complex [Rh(OTf)(trop2NH)(PPh3)] employed as molecular active site in an anode of an OMFC selectively oxidizes a number of renewable diols, such as ethylene glycol , 1,2‐propanediol (1,2‐P), 1,3‐propanediol (1,3‐P), and 1,4‐butanediol (1,4‐B) to their corresponding mono‐carboxylates. The electrochemical performance of this molecular catalyst is discussed, with the aim to achieve cogeneration of electricity and valuable chemicals in a highly selective electrooxidation from diol precursors.
Cellmates: Organometallic fuel cells (OMFC) catalyze the selective electrooxidation of renewable diols such as ethylene glycol, 1,2‐propanediol, 1,3‐propanediol, and 1,4‐butanediol, simultaneously providing high power densities and chemicals of industrial importance. [Rh(OTf)(trop2NH)(PPh3)], an organometallic complex, is employed as molecular active site in an anode of an OMFC and its electrochemical performance is evaluated.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><pmid>25082272</pmid><doi>10.1002/cssc.201402316</doi><tpages>4</tpages></addata></record> |
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| subjects | Bioelectric Energy Sources carboxylates Electrochemistry energy conversion Fuel cells Glycols - chemistry Organometallic Compounds - chemistry organometallic fuel cell oxidation Oxidation-Reduction renewable alcohols rhodium Substrate Specificity |
| title | Energy and Chemicals from the Selective Electrooxidation of Renewable Diols by Organometallic Fuel Cells |
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