Energy and Chemicals from the Selective Electrooxidation of Renewable Diols by Organometallic Fuel Cells

Organometallic fuel cells catalyze the selective electrooxidation of renewable diols, simultaneously providing high power densities and chemicals of industrial importance. It is shown that the unique organometallic complex [Rh(OTf)(trop2NH)(PPh3)] employed as molecular active site in an anode of an OMFC selectively oxidizes a number of renewable diols, such as ethylene glycol , 1,2‐propanediol (1,2‐P), 1,3‐propanediol (1,3‐P), and 1,4‐butanediol (1,4‐B) to their corresponding mono‐carboxylates. The electrochemical performance of this molecular catalyst is discussed, with the aim to achieve cogeneration of electricity and valuable chemicals in a highly selective electrooxidation from diol precursors. Cellmates: Organometallic fuel cells (OMFC) catalyze the selective electrooxidation of renewable diols such as ethylene glycol, 1,2‐propanediol, 1,3‐propanediol, and 1,4‐butanediol, simultaneously providing high power densities and chemicals of industrial importance. [Rh(OTf)(trop2NH)(PPh3)], an organometallic complex, is employed as molecular active site in an anode of an OMFC and its electrochemical performance is evaluated.