Catalytic Asymmetric Intermolecular Bromoesterification of Unfunctionalized Olefins

Catalytic Asymmetric Intermolecular Bromoesterification of Unfunctionalized Olefins

An asymmetric intermolecular bromoesterification of unfunctionalized olefins catalyzed by (DHQD)2PHAL is described. Optically active bromoesters can be obtained with up to 92% ee.

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Veröffentlicht in:Organic letters 2014-07, Vol.16 (14), p.3728-3731
Hauptverfasser: Li, Lijun, Su, Cunxiang, Liu, Xiaoqin, Tian, Hua, Shi, Yian
Format: Artikel
Sprache:eng
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Zusammenfassung:An asymmetric intermolecular bromoesterification of unfunctionalized olefins catalyzed by (DHQD)2PHAL is described. Optically active bromoesters can be obtained with up to 92% ee.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol501542r