Münchnones-New Facets after 50 Years

Münchnones-New Facets after 50 Years

Developed and named 50 years ago in Munich, the mesoionic münchnones have had an astonishing career. New multicomponent reactions and enantioselective cycloadditions are discussed. They demonstrate the versatility of the münchnone approach to nitrogen heterocycles.

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Bibliographische Detailangaben
Veröffentlicht in:Angewandte Chemie International Edition 2014-09, Vol.53 (37), p.9708-9710
Hauptverfasser: Reissig, Hans-Ulrich, Zimmer, Reinhold
Format: Artikel
Sprache:eng
Schlagworte:
1,3‐dipolar cycloadditions
3-dipolar cycloadditions
alkynes
asymmetric catalysis
Catalysis
Cyclization
multicomponent reactions
Oxazoles
pyrroles
Pyrroles - metabolism
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Beschreibung
Zusammenfassung:Developed and named 50 years ago in Munich, the mesoionic münchnones have had an astonishing career. New multicomponent reactions and enantioselective cycloadditions are discussed. They demonstrate the versatility of the münchnone approach to nitrogen heterocycles.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201405092