Non-humidified proton conduction between a Lewis acid-base pair

Non-humidified proton conduction between a Lewis acid-base pair

Proton conduction in zirconium sulphate (ZrSO4) composed of a Lewis acid-base pair was studied. ZrSO4 exhibits non-humidified proton conductivity, comparable to other proton conductors under similar conditions. Ab initio calculation shows that a proton transfers in ZrSO4 from a Lewis acid to a Lewis...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Physical chemistry chemical physics : PCCP 2013-01, Vol.15 (33), p.13814-13817
Hauptverfasser: OGAWA, Takaya, OHASHI, Hidenori, TAMAKI, Takanori, YAMAGUCHI, Takeo
Format: Artikel
Sprache:eng
Schlagworte:
Carriers
Chemistry
Conductors
Exact sciences and technology
General and physical chemistry
Lewis acid
Lewis base
Physical chemistry
Proton conduction
Sulfates
Zirconium
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Proton conduction in zirconium sulphate (ZrSO4) composed of a Lewis acid-base pair was studied. ZrSO4 exhibits non-humidified proton conductivity, comparable to other proton conductors under similar conditions. Ab initio calculation shows that a proton transfers in ZrSO4 from a Lewis acid to a Lewis base without a proton carrier.
ISSN:1463-9076
1463-9084
DOI:10.1039/c3cp51697k