Red-luminescent biphosphine stabilized 'Cu₁₂S₆' cluster molecules

Red-luminescent biphosphine stabilized 'Cu₁₂S₆' cluster molecules

The synthesis, molecular structures and luminescence properties of two 'Cu12S6' cluster molecules with stabilizing bidentate phosphine ligands are described. Both display in the solid state at ambient temperature high photoluminescence quantum yields (≥48%) and good stability towards oxyge...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2014-09, Vol.50 (75), p.11043-11045
Hauptverfasser: Yang, Xiao-Xun, Issac, Ibrahim, Lebedkin, Sergej, Kühn, Michael, Weigend, Florian, Fenske, Dieter, Fuhr, Olaf, Eichhöfer, Andreas
Format: Artikel
Sprache:eng
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Zusammenfassung:The synthesis, molecular structures and luminescence properties of two 'Cu12S6' cluster molecules with stabilizing bidentate phosphine ligands are described. Both display in the solid state at ambient temperature high photoluminescence quantum yields (≥48%) and good stability towards oxygen.
ISSN:1364-548X
DOI:10.1039/c4cc04702h