The Remarkable Stable Emerald Green C60 F15 [CBr(CO2 Et)2 ]3 : The First [60]Fullerene That Is also the First [18]Trannulene

The Remarkable Stable Emerald Green C60 F15 [CBr(CO2 Et)2 ]3 : The First [60]Fullerene That Is also the First [18]Trannulene

It is both an [18]trannulene and a [60]fullerene. It is aromatic and a hexa-substituted benzene. It is formed by the first proven example of an SN 2' reaction in a fullerene. It is intensely colored and stable. It is C60 F15 [CBr(CO2 Et)2 ]3 , the first example of a new class of fullerene deriv...

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Veröffentlicht in:Angewandte Chemie International Edition 2001, Vol.40 (16), p.2989-2992
Hauptverfasser: Wei, X W, Darwish, A D, Boltalina, O V, Hitchcock, P B, Street, J M, Taylor, R
Format: Artikel
Sprache:eng
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Zusammenfassung:It is both an [18]trannulene and a [60]fullerene. It is aromatic and a hexa-substituted benzene. It is formed by the first proven example of an SN 2' reaction in a fullerene. It is intensely colored and stable. It is C60 F15 [CBr(CO2 Et)2 ]3 , the first example of a new class of fullerene derivatives (see Schlegel diagram).
ISSN:1433-7851
DOI:10.1002/1521-3773(20010817)40:16<2989::AID-ANIE2989>3.0.CO;2-0