Rational Design of Synthetic Nanoparticles with a Large Reversible Shift of Acid Dissociation Constants: Proton Imprinting in Stimuli Responsive Nanogel Particles
Temperature‐responsive nanogel particles with acids exhibiting large and reversible pK a shift are prepared by an ion‐imprinting polymerization of stimuli responsive monomers, cross‐linkers, and acidic monomers using protons as a template. The principles employed here should be broadly applicable to...
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| Veröffentlicht in: | Advanced materials (Weinheim) 2014-06, Vol.26 (22), p.3718-3723 |
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| container_title | Advanced materials (Weinheim) |
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| creator | Hoshino, Yu Ohashi, Ryohei C. Miura, Yoshiko |
| description | Temperature‐responsive nanogel particles with acids exhibiting large and reversible pK
a shift are prepared by an ion‐imprinting polymerization of stimuli responsive monomers, cross‐linkers, and acidic monomers using protons as a template. The principles employed here should be broadly applicable to other stimuli‐responsive materials and will be an integral step in the production of active proton transporter. |
| doi_str_mv | 10.1002/adma.201305957 |
| format | Article |
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| fulltext | fulltext |
| identifier | ISSN: 0935-9648 |
| ispartof | Advanced materials (Weinheim), 2014-06, Vol.26 (22), p.3718-3723 |
| issn | 0935-9648 1521-4095 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1551085803 |
| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Constants Crosslinking Integrals ion imprinting molecular recognition Monomers Nanoparticles Nanostructure pKa shift reversible capture Stimuli Transporter |
| title | Rational Design of Synthetic Nanoparticles with a Large Reversible Shift of Acid Dissociation Constants: Proton Imprinting in Stimuli Responsive Nanogel Particles |
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