Synthesis, evolution and hydrogen storage properties of ZnV sub(2)O sub(4) glomerulus nano/microspheres: A prospective material for energy storage

We present first study on ZnV sub(2)O sub(4) glomerulus nano/microspheres synthesize by template free route to expose its hydrogen storage potential. Besides this the evolution of nano/microspheres has been investigated in detail. To reveal possible growth mechanism of these spheres, time-dependent...

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Veröffentlicht in:International journal of hydrogen energy 2014-05, Vol.39 (15), p.7842-7851
Hauptverfasser: Butt, Faheem K, Cao, Chuanbao, Wan, Qi, Li, Ping, Idrees, Faryal, Tahir, Muhammad, Khan, Waheed S, Ali, Zulfiqar, Zapata, Maximiliano JM, Safdar, Muhammad, Qu, Xuanhui
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Sprache:eng
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Zusammenfassung:We present first study on ZnV sub(2)O sub(4) glomerulus nano/microspheres synthesize by template free route to expose its hydrogen storage potential. Besides this the evolution of nano/microspheres has been investigated in detail. To reveal possible growth mechanism of these spheres, time-dependent experiments are performed. Reitveld analysis is taken into account for calculation of lattice parameters, crystallite size and strain. From our results, a correlation between lattice parameters and crystallite size is observed. The strain decreases with the increase in reaction time. Hydrogen storage measurement reveals potential of ZnV sub(2)O sub(4) nanospheres as a prospective material for energy storage applications. These studies can open new avenue of research for hydrogen storage in spinel oxide materials.
ISSN:0360-3199
DOI:10.1016/j.ijhydene.2014.03.033