Guest control of structure in porous organic cages

Guest control of structure in porous organic cages

Two porous organic cages with different thermodynamic polymorphs were induced by co-solvents to interchange their crystal packing modes, thus achieving guest-mediated control over solid-state porosity. In situ crystallography allows the effect of the co-solvent guests on these structural interconver...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2014-08, Vol.50 (67), p.9465-9468
Hauptverfasser: Little, Marc A, Chong, Samantha Y, Schmidtmann, Marc, Hasell, Tom, Cooper, Andrew I
Format: Artikel
Sprache:eng
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Zusammenfassung:Two porous organic cages with different thermodynamic polymorphs were induced by co-solvents to interchange their crystal packing modes, thus achieving guest-mediated control over solid-state porosity. In situ crystallography allows the effect of the co-solvent guests on these structural interconversions to be understood.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc04158e