Synthesis of Structurally Ordered Pt3Ti and Pt3V Nanoparticles as Methanol Oxidation Catalysts

Structurally ordered Pt3Ti or Pt3V intermetallic nanoparticle catalysts with ultrasmall particle sizes have never been successfully synthesized. Herein, we present a KCl-nanoparticle method to successfully provide such compounds. These two catalysts show enhanced catalytic activity and stability for...

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Veröffentlicht in:Journal of the American Chemical Society 2014-07, Vol.136 (29), p.10206-10209
Hauptverfasser: Cui, Zhiming, Chen, Hao, Zhao, Mengtian, Marshall, Daniel, Yu, Yingchao, Abruña, Héctor, DiSalvo, Francis J
Format: Artikel
Sprache:eng
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Zusammenfassung:Structurally ordered Pt3Ti or Pt3V intermetallic nanoparticle catalysts with ultrasmall particle sizes have never been successfully synthesized. Herein, we present a KCl-nanoparticle method to successfully provide such compounds. These two catalysts show enhanced catalytic activity and stability for methanol oxidation compared to pure Pt.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja504573a