Coordination reaction between tetraphenylporphyrin and nickel on a TiO2(110) surface

Coordination reaction between tetraphenylporphyrin and nickel on a TiO2(110) surface

In situ metalation of tetraphenylporphyrin (2HTPP) (sub)monolayers with Ni on a TiO2(110) surface to nickel(II)-tetraphenylporphyrin (NiTPP) depends on temperature and order of deposition, and affects conformation and bonding geometry of the porphyrin.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2014-08, Vol.50 (61), p.8291-8294
Hauptverfasser: Wang, Cici, Fan, Qitang, Hu, Shanwei, Ju, Huanxin, Feng, Xuefei, Han, Yong, Pan, Haibin, Zhu, Junfa, Gottfried, J Michael
Format: Artikel
Sprache:eng
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Zusammenfassung:In situ metalation of tetraphenylporphyrin (2HTPP) (sub)monolayers with Ni on a TiO2(110) surface to nickel(II)-tetraphenylporphyrin (NiTPP) depends on temperature and order of deposition, and affects conformation and bonding geometry of the porphyrin.
ISSN:1364-548X
DOI:10.1039/c4cc02919d