Energy-transfer from ultra-small Au nanoclusters to Er³⁺ ions: a short-range mechanism
Sub-nanometric Au nanoclusters are known to act as very efficient sensitizers for the luminescent emission of Er(3+) ions in silica through a non-resonant broad-band energy-transfer mechanism. In the present work the energy-transfer process is investigated in detail by room temperature photoluminesc...
Gespeichert in:
| Veröffentlicht in: | Physical chemistry chemical physics : PCCP 2014-08, Vol.16 (29), p.15158-15163 |
|---|---|
| Hauptverfasser: | , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 15163 |
|---|---|
| container_issue | 29 |
| container_start_page | 15158 |
| container_title | Physical chemistry chemical physics : PCCP |
| container_volume | 16 |
| creator | Cesca, Tiziana Kalinic, Boris Michieli, Niccolò Maurizio, Chiara Scian, Carlo Devaraju, Gurram Battaglin, Giancarlo Mazzoldi, Paolo Mattei, Giovanni |
| description | Sub-nanometric Au nanoclusters are known to act as very efficient sensitizers for the luminescent emission of Er(3+) ions in silica through a non-resonant broad-band energy-transfer mechanism. In the present work the energy-transfer process is investigated in detail by room temperature photoluminescence characterization of Er and Au co-implanted silica systems in which a different degree of coupling between Er(3+) ions and Au nanoclusters is obtained. The results allow us to definitely demonstrate the short-range nature of the interaction in agreement with non-radiative energy-transfer mechanisms. Moreover, an upper limit to the interaction length is also set by the Au-Au intercluster semi-distance which is smaller than 2.4 nm in the present case. |
| doi_str_mv | 10.1039/c4cp01680g |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1543280736</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1543280736</sourcerecordid><originalsourceid>FETCH-LOGICAL-c217t-66251ab2b37b951776b388b1199bba99398cd1bb9c9c3ac812f7e938c2e196ae3</originalsourceid><addsrcrecordid>eNpFkL1OwzAURi0EoqWw8ADII0IK-MaJY7NVVfmRKrHAwBTZrtMGJXHxTYaOfSY2Rh6FJyGopUz3u9LRGQ4h58CugXF1YxO7YiAkWxyQISSCR4rJ5HC_MzEgJ4hvjDFIgR-TQZwonqaghuR12riwWEdt0A0WLtAi-Jp2Vf9HWOuqouOONrrxtuqwdQFp6-k0fH18bz5p6Ru8pZri0oc26g0LR2tnl7opsT4lR4Wu0J3t7oi83E2fJw_R7On-cTKeRTaGrI2EiFPQJjY8MyqFLBOGS2kAlDJGK8WVtHMwRlllubYS4iJziksbO1BCOz4il1vvKvj3zmGb1yVaV1W6cb7DHNKEx5JlXPTo1Ra1wSMGV-SrUNY6rHNg-W_K_D9lD1_svJ2p3XyP_rXjPxO2cNg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1543280736</pqid></control><display><type>article</type><title>Energy-transfer from ultra-small Au nanoclusters to Er³⁺ ions: a short-range mechanism</title><source>Royal Society Of Chemistry Journals</source><source>Alma/SFX Local Collection</source><creator>Cesca, Tiziana ; Kalinic, Boris ; Michieli, Niccolò ; Maurizio, Chiara ; Scian, Carlo ; Devaraju, Gurram ; Battaglin, Giancarlo ; Mazzoldi, Paolo ; Mattei, Giovanni</creator><creatorcontrib>Cesca, Tiziana ; Kalinic, Boris ; Michieli, Niccolò ; Maurizio, Chiara ; Scian, Carlo ; Devaraju, Gurram ; Battaglin, Giancarlo ; Mazzoldi, Paolo ; Mattei, Giovanni</creatorcontrib><description>Sub-nanometric Au nanoclusters are known to act as very efficient sensitizers for the luminescent emission of Er(3+) ions in silica through a non-resonant broad-band energy-transfer mechanism. In the present work the energy-transfer process is investigated in detail by room temperature photoluminescence characterization of Er and Au co-implanted silica systems in which a different degree of coupling between Er(3+) ions and Au nanoclusters is obtained. The results allow us to definitely demonstrate the short-range nature of the interaction in agreement with non-radiative energy-transfer mechanisms. Moreover, an upper limit to the interaction length is also set by the Au-Au intercluster semi-distance which is smaller than 2.4 nm in the present case.</description><identifier>ISSN: 1463-9076</identifier><identifier>EISSN: 1463-9084</identifier><identifier>DOI: 10.1039/c4cp01680g</identifier><identifier>PMID: 24935519</identifier><language>eng</language><publisher>England</publisher><ispartof>Physical chemistry chemical physics : PCCP, 2014-08, Vol.16 (29), p.15158-15163</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c217t-66251ab2b37b951776b388b1199bba99398cd1bb9c9c3ac812f7e938c2e196ae3</citedby><cites>FETCH-LOGICAL-c217t-66251ab2b37b951776b388b1199bba99398cd1bb9c9c3ac812f7e938c2e196ae3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,782,786,27931,27932</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/24935519$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Cesca, Tiziana</creatorcontrib><creatorcontrib>Kalinic, Boris</creatorcontrib><creatorcontrib>Michieli, Niccolò</creatorcontrib><creatorcontrib>Maurizio, Chiara</creatorcontrib><creatorcontrib>Scian, Carlo</creatorcontrib><creatorcontrib>Devaraju, Gurram</creatorcontrib><creatorcontrib>Battaglin, Giancarlo</creatorcontrib><creatorcontrib>Mazzoldi, Paolo</creatorcontrib><creatorcontrib>Mattei, Giovanni</creatorcontrib><title>Energy-transfer from ultra-small Au nanoclusters to Er³⁺ ions: a short-range mechanism</title><title>Physical chemistry chemical physics : PCCP</title><addtitle>Phys Chem Chem Phys</addtitle><description>Sub-nanometric Au nanoclusters are known to act as very efficient sensitizers for the luminescent emission of Er(3+) ions in silica through a non-resonant broad-band energy-transfer mechanism. In the present work the energy-transfer process is investigated in detail by room temperature photoluminescence characterization of Er and Au co-implanted silica systems in which a different degree of coupling between Er(3+) ions and Au nanoclusters is obtained. The results allow us to definitely demonstrate the short-range nature of the interaction in agreement with non-radiative energy-transfer mechanisms. Moreover, an upper limit to the interaction length is also set by the Au-Au intercluster semi-distance which is smaller than 2.4 nm in the present case.</description><issn>1463-9076</issn><issn>1463-9084</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNpFkL1OwzAURi0EoqWw8ADII0IK-MaJY7NVVfmRKrHAwBTZrtMGJXHxTYaOfSY2Rh6FJyGopUz3u9LRGQ4h58CugXF1YxO7YiAkWxyQISSCR4rJ5HC_MzEgJ4hvjDFIgR-TQZwonqaghuR12riwWEdt0A0WLtAi-Jp2Vf9HWOuqouOONrrxtuqwdQFp6-k0fH18bz5p6Ru8pZri0oc26g0LR2tnl7opsT4lR4Wu0J3t7oi83E2fJw_R7On-cTKeRTaGrI2EiFPQJjY8MyqFLBOGS2kAlDJGK8WVtHMwRlllubYS4iJziksbO1BCOz4il1vvKvj3zmGb1yVaV1W6cb7DHNKEx5JlXPTo1Ra1wSMGV-SrUNY6rHNg-W_K_D9lD1_svJ2p3XyP_rXjPxO2cNg</recordid><startdate>20140807</startdate><enddate>20140807</enddate><creator>Cesca, Tiziana</creator><creator>Kalinic, Boris</creator><creator>Michieli, Niccolò</creator><creator>Maurizio, Chiara</creator><creator>Scian, Carlo</creator><creator>Devaraju, Gurram</creator><creator>Battaglin, Giancarlo</creator><creator>Mazzoldi, Paolo</creator><creator>Mattei, Giovanni</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20140807</creationdate><title>Energy-transfer from ultra-small Au nanoclusters to Er³⁺ ions: a short-range mechanism</title><author>Cesca, Tiziana ; Kalinic, Boris ; Michieli, Niccolò ; Maurizio, Chiara ; Scian, Carlo ; Devaraju, Gurram ; Battaglin, Giancarlo ; Mazzoldi, Paolo ; Mattei, Giovanni</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c217t-66251ab2b37b951776b388b1199bba99398cd1bb9c9c3ac812f7e938c2e196ae3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Cesca, Tiziana</creatorcontrib><creatorcontrib>Kalinic, Boris</creatorcontrib><creatorcontrib>Michieli, Niccolò</creatorcontrib><creatorcontrib>Maurizio, Chiara</creatorcontrib><creatorcontrib>Scian, Carlo</creatorcontrib><creatorcontrib>Devaraju, Gurram</creatorcontrib><creatorcontrib>Battaglin, Giancarlo</creatorcontrib><creatorcontrib>Mazzoldi, Paolo</creatorcontrib><creatorcontrib>Mattei, Giovanni</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Physical chemistry chemical physics : PCCP</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Cesca, Tiziana</au><au>Kalinic, Boris</au><au>Michieli, Niccolò</au><au>Maurizio, Chiara</au><au>Scian, Carlo</au><au>Devaraju, Gurram</au><au>Battaglin, Giancarlo</au><au>Mazzoldi, Paolo</au><au>Mattei, Giovanni</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Energy-transfer from ultra-small Au nanoclusters to Er³⁺ ions: a short-range mechanism</atitle><jtitle>Physical chemistry chemical physics : PCCP</jtitle><addtitle>Phys Chem Chem Phys</addtitle><date>2014-08-07</date><risdate>2014</risdate><volume>16</volume><issue>29</issue><spage>15158</spage><epage>15163</epage><pages>15158-15163</pages><issn>1463-9076</issn><eissn>1463-9084</eissn><abstract>Sub-nanometric Au nanoclusters are known to act as very efficient sensitizers for the luminescent emission of Er(3+) ions in silica through a non-resonant broad-band energy-transfer mechanism. In the present work the energy-transfer process is investigated in detail by room temperature photoluminescence characterization of Er and Au co-implanted silica systems in which a different degree of coupling between Er(3+) ions and Au nanoclusters is obtained. The results allow us to definitely demonstrate the short-range nature of the interaction in agreement with non-radiative energy-transfer mechanisms. Moreover, an upper limit to the interaction length is also set by the Au-Au intercluster semi-distance which is smaller than 2.4 nm in the present case.</abstract><cop>England</cop><pmid>24935519</pmid><doi>10.1039/c4cp01680g</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1463-9076 |
| ispartof | Physical chemistry chemical physics : PCCP, 2014-08, Vol.16 (29), p.15158-15163 |
| issn | 1463-9076 1463-9084 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1543280736 |
| source | Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
| title | Energy-transfer from ultra-small Au nanoclusters to Er³⁺ ions: a short-range mechanism |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-03T20%3A57%3A01IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Energy-transfer%20from%20ultra-small%20Au%20nanoclusters%20to%20Er%C2%B3%E2%81%BA%20ions:%20a%20short-range%20mechanism&rft.jtitle=Physical%20chemistry%20chemical%20physics%20:%20PCCP&rft.au=Cesca,%20Tiziana&rft.date=2014-08-07&rft.volume=16&rft.issue=29&rft.spage=15158&rft.epage=15163&rft.pages=15158-15163&rft.issn=1463-9076&rft.eissn=1463-9084&rft_id=info:doi/10.1039/c4cp01680g&rft_dat=%3Cproquest_cross%3E1543280736%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1543280736&rft_id=info:pmid/24935519&rfr_iscdi=true |