Alumina nanofibers obtained via electrospinning of pseudo-boehmite sol/PVP solution

Alumina nanofibers were fabricated by calcination of the polyvinylpyrrolidone (PVP)/pseudo-boehmite nanocomposite precursor fibers formed by electrospinning PVP/ethanol solution of dispersed pseudo-boehmite nanoparticles with and without additive of silica. The evolution of the phase, mechanical pro...

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Veröffentlicht in:Journal of sol-gel science and technology 2014-04, Vol.70 (1), p.72-80
Hauptverfasser: Zhao, Zhihua, Shen, Xiaoqing, Yao, Hongchang, Wang, Jianshe, Chen, Jinzhou, Li, Zhongjun
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Sprache:eng
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Zusammenfassung:Alumina nanofibers were fabricated by calcination of the polyvinylpyrrolidone (PVP)/pseudo-boehmite nanocomposite precursor fibers formed by electrospinning PVP/ethanol solution of dispersed pseudo-boehmite nanoparticles with and without additive of silica. The evolution of the phase, mechanical property and morphological features of the calcined fibers were studied and the effect of adding SiO 2 on the phase transformation of alumina was discussed. Adding SiO 2 can retard the phase transformation of γ-Al 2 O 3 to α-Al 2 O 3 and therefore inhibit the growth of alumina grains during calcination. Upon calcining the precursor fibers with 4 wt% SiO 2 additive at 1,300 °C, continuous alumina nanofibers with diameter ranging from 300 to 800 nm were obtained. These continuous nanofibers exhibited good flexibility and could be very promising for applications in filtration and catalyst support.
ISSN:0928-0707
1573-4846
DOI:10.1007/s10971-014-3276-x