Controlled self-assembly of porphyrin/fullerene donor-acceptor complex in a polymer thin film

ABSTRACT Thin films composed of polycyclohexane (PCHE), zinc(II)‐5,10,15,20‐tetra‐(2‐naphthyl)porphyrin (ZnTNpP), and [6,6]‐phenyl‐C61‐butyric acid methyl ester (PCBM) blends are prepared to investigate their potential for the controlled self‐assembly of a porphyrin/fullerene donor–acceptor complex...

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Veröffentlicht in:	Journal of polymer science. Part B, Polymer physics Polymer physics, 2014-06, Vol.52 (11), p.743-746
Hauptverfasser:	Natori, Itaru, Natori, Shizue, Hanawa, Naoki, Ogino, Kenji
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences Blends Compatibility Exact sciences and technology Forms of application and semi-finished materials Fullerenes phase separation Polymer blends Polymer industry, paints, wood Polymeric films porphyrin/fullerene donor-acceptor complex Porphyrins Self assembly Sheets and films Technology of polymers Thin films
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Zusammenfassung:	ABSTRACT Thin films composed of polycyclohexane (PCHE), zinc(II)‐5,10,15,20‐tetra‐(2‐naphthyl)porphyrin (ZnTNpP), and [6,6]‐phenyl‐C61‐butyric acid methyl ester (PCBM) blends are prepared to investigate their potential for the controlled self‐assembly of a porphyrin/fullerene donor–acceptor complex in a polymer thin film. The compatibilities of PCHE/PCBM (p), PCHE/ZnTNpP (q), and ZnTNpP/PCBM (r) in these blends have a significant effect on the dispersion of the ZnTNpP/PCBM donor–acceptor complex in the PCHE thin film. When the compatibilities are p
ISSN:	0887-6266 1099-0488
DOI:	10.1002/polb.23488