Direct grafting of poly(pentafluorophenyl acrylate) onto oxides: versatile substrates for reactive microcapillary printing and self-sorting modification

Direct grafting of poly(pentafluorophenyl acrylate) onto oxides: versatile substrates for reactive microcapillary printing and self-sorting modification

Poly(pentafluorophenyl acrylate) was covalently attached to silicon oxide through the direct coupling of the reactive ester to surface silanol groups. Subsequently, reactive microcapillary printing (R-μCaP) and a one-pot, self-sorting postpolymerization modification reaction were used to generate pa...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2014-01, Vol.50 (40), p.5307-5309
Hauptverfasser: Arnold, Rachelle M, McNitt, Christopher D, Popik, Vladimir V, Locklin, Jason
Format: Artikel
Sprache:eng
Schlagworte:
Acrylates
Covalence
Esters
Grafting
Joining
Oxides
Printing
Silicon oxides
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Zusammenfassung:Poly(pentafluorophenyl acrylate) was covalently attached to silicon oxide through the direct coupling of the reactive ester to surface silanol groups. Subsequently, reactive microcapillary printing (R-μCaP) and a one-pot, self-sorting postpolymerization modification reaction were used to generate patterns of spatially resolved chemical functionality.
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc47597b