Topological behavior mimicking ethylene–hexene copolymers using branched lactones and macrolactones

Topological behavior mimicking ethylene–hexene copolymers using branched lactones and macrolactones

A new approach towards polyolefin-like copolyesters is introduced based on a single set of reaction conditions. The delicate balance between steric hindrance and monomer reactivity determines whether random or block copolymers are formed.

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Veröffentlicht in:Polymer chemistry 2014-01, Vol.5 (10), p.3306-3310
Hauptverfasser: Jasinska-Walc, Lidia, Hansen, Michael Ryan, Dudenko, Dmytro, Rozanski, Artur, Bouyahyi, Miloud, Wagner, Manfred, Graf, Robert, Duchateau, Robbert
Format: Artikel
Sprache:eng
Schlagworte:
Block copolymers
Branched
Copolymers
Lactones
Monomers
Polymer chemistry
Steric hindrance
Topology
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Beschreibung
Zusammenfassung:A new approach towards polyolefin-like copolyesters is introduced based on a single set of reaction conditions. The delicate balance between steric hindrance and monomer reactivity determines whether random or block copolymers are formed.
ISSN:1759-9954
1759-9962
DOI:10.1039/C3PY01754K