Infrared absorption spectra of methylidene radicals in solid neon

Infrared absorption spectra of methylidene radicals in solid neon

Infrared absorption lines of methylidene - 12 C 1 H, 13 C 1 H, and 12 C 2 H - dispersed in solid neon at 3 K, recorded after photolysis of methane precursors with vacuum-ultraviolet light at 121.6 nm, serve as signatures of these trapped radicals. Infrared absorption lines of methylidene radicals di...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2014-07, Vol.5 (59), p.7968-797
Hauptverfasser: Lu, Hsiao-Chi, Lo, Jen-Iu, Lin, Meng-Yeh, Peng, Yu-Chain, Chou, Sheng-Lung, Cheng, Bing-Ming, Ogilvie, J. F
Format: Artikel
Sprache:eng
Schlagworte:
Infrared absorption
Infrared signatures
Methane
Neon
Photolysis
Precursors
Radicals
Spectra
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Zusammenfassung:Infrared absorption lines of methylidene - 12 C 1 H, 13 C 1 H, and 12 C 2 H - dispersed in solid neon at 3 K, recorded after photolysis of methane precursors with vacuum-ultraviolet light at 121.6 nm, serve as signatures of these trapped radicals. Infrared absorption lines of methylidene radicals dispersed in solid neon at 3 K, recorded after photolysis of methane precursors with vacuum-ultraviolet light.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc02970d