Enantioselective transesterification of (±)-1-phenylundecan-3-ol catalyzed by the lipase from Burkholderia cepacia

Enantioselective transesterification of (±)-1-phenylundecan-3-ol catalyzed by the lipase from Burkholderia cepacia

Enantiomerically enriched ( R )- and ( S )-1-phenylundecan-3-ols were obtained by kinetic resolution of the racemate with vinyl acetate in ButOMe at 20 °C using the lipase from Burkholderia cepacia . The absolute configuration of the enantiomers was confirmed by a direct stereochemical correlation w...

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Veröffentlicht in:Russian chemical bulletin 2013-09, Vol.62 (9), p.2041-2045
Hauptverfasser: Vlasyuk, A. L., Voblikova, V. A., Gamalevich, G. D., Serebryakov, E. P.
Format: Artikel
Sprache:eng
Schlagworte:
Burkholderia cepacia
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Full Articles
Inorganic Chemistry
Organic Chemistry
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Zusammenfassung:Enantiomerically enriched ( R )- and ( S )-1-phenylundecan-3-ols were obtained by kinetic resolution of the racemate with vinyl acetate in ButOMe at 20 °C using the lipase from Burkholderia cepacia . The absolute configuration of the enantiomers was confirmed by a direct stereochemical correlation with the known ( R )- and ( S )-dodecanolides.
ISSN:1066-5285
1573-9171
DOI:10.1007/s11172-013-0296-6