A note on the polarographic behavior of the Cu(II) ion selective electrode in seawater

The non-Nernstian behavior of a solid-state cupric ion-selective electrode in seawater is attributed to a reduction of Cu 2+ at the surface in accordance with a suggestion made in the literature. This ‘polarographic’ behaviour was demonstrated by showing that the electrode potential is affected by m...

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Veröffentlicht in:Marine chemistry 1981-01, Vol.10 (3), p.249-255
Hauptverfasser: Zirino, Alberto, Seligman, Peter F.
Format: Artikel
Sprache:eng
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Zusammenfassung:The non-Nernstian behavior of a solid-state cupric ion-selective electrode in seawater is attributed to a reduction of Cu 2+ at the surface in accordance with a suggestion made in the literature. This ‘polarographic’ behaviour was demonstrated by showing that the electrode potential is affected by molecular oxygen in solution.
ISSN:0304-4203
1872-7581
DOI:10.1016/0304-4203(81)90045-1