The synthesis and structure of chiral enamine N-oxides

Chiral enamine N-oxides have been synthesised by a diastereoselective intermolecular reverse-Cope cycloaddition reaction between chiral hydroxylamines and activated acetylenes. Their structures have been investigated by NMR, X-ray crystallography and computational methods.

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Bibliographische Detailangaben
Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2014-01, Vol.50 (55), p.7336-7339
Hauptverfasser:	O'Neil, I A, McConville, M, Zhou, K, Brooke, C, Robertson, C M, Berry, N G
Format:	Artikel
Sprache:	eng
Schlagworte:	Crystallography, X-Ray Cycloaddition Reaction Magnetic Resonance Spectroscopy Models, Molecular Oxides - chemical synthesis Oxides - chemistry Stereoisomerism
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	Chiral enamine N-oxides have been synthesised by a diastereoselective intermolecular reverse-Cope cycloaddition reaction between chiral hydroxylamines and activated acetylenes. Their structures have been investigated by NMR, X-ray crystallography and computational methods.
ISSN:	1359-7345 1364-548X
DOI:	10.1039/c3cc47928e