Enhanced charge-discharge properties of SnO2 nanocrystallites in confined carbon nanospace

Almost perfect embedding of SnO2 nanocrystallites in carbon nanopores was achieved by in situ synthesis using vaporized SnCl2 and silica opal-derived nanoporous carbons. The reversibility of SnO2-Sn conversion and Sn-Li alloying/de-alloying reactions was greatly enhanced by the confinement in regula...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2014-07, Vol.50 (54), p.7143-7146
Hauptverfasser: Oro, Shinji, Urita, Koki, Moriguchi, Isamu
Format: Artikel
Sprache:eng
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Zusammenfassung:Almost perfect embedding of SnO2 nanocrystallites in carbon nanopores was achieved by in situ synthesis using vaporized SnCl2 and silica opal-derived nanoporous carbons. The reversibility of SnO2-Sn conversion and Sn-Li alloying/de-alloying reactions was greatly enhanced by the confinement in regulated carbon nanospace.
ISSN:1364-548X
DOI:10.1039/c4cc02716g