Performance evaluation of anode-supported Gd0.1Ce0.9O1.95 cell with electrospun La0.6Sr0.4Co0.2Fe0.8O3−δ-Gd0.1Ce0.9O1.95 cathode

A cathode performance is considered as a key factor to enhance the power efficiency of intermediate temperature solid oxide fuel cells (IT-SOFCs). In order to improve the cathode performance, La0.6Sr0.4Co0.2Fe0.8O3−δ-Gd0.1Ce0.9O1.95 (LSCF-GDC) cathode is fabricated by electrospinning method. The thr...

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Veröffentlicht in:Electrochimica acta 2013-10, Vol.108, p.356-360
Hauptverfasser: Lee, Jin Goo, Lee, Chan Min, Park, Myeong Geun, Jung, Sang-Jin, Shul, Yong Gun
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Sprache:eng
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Zusammenfassung:A cathode performance is considered as a key factor to enhance the power efficiency of intermediate temperature solid oxide fuel cells (IT-SOFCs). In order to improve the cathode performance, La0.6Sr0.4Co0.2Fe0.8O3−δ-Gd0.1Ce0.9O1.95 (LSCF-GDC) cathode is fabricated by electrospinning method. The three-dimensional fiber network cathode has high porosity, continuous pathway for charge transfer and increased triple phase boundary sites (TPB). The electrospun cathode is applied to Ni-GDC anode-supported Gd0.1Ce0.9O1.95 cell. The electrical properties of the electrospun LSCF-GDC cathode are compared with the conventional LSCF-GDC powder cathode. The polarization resistance and maximum power density of the cell with the electrospun cathode are about 0.08Ωcm2 and 0.85Wcm−2 at 650°C, respectively. The power density of the cell with the electrospun cathode is approximately two times higher than 0.45Wcm−2 (at 650°C) of the cell with the conventional LSCF-GDC cathode. This result demonstrates that the application of the electrospun LSCF-GDC cathode can be a promising method for enhancing the electrical performance of an anode-supported GDC cell at intermediate temperatures.
ISSN:0013-4686
1873-3859
DOI:10.1016/j.electacta.2013.06.091