Molecular structure of (cyanomethoxy)(dimethylamino)methane as studied by gas-phase electron diffraction and quantum-chemical calculations
The molecular structure of (cyanomethoxy)(dimethylamino)methane in the gas phase is investigated by means of gas-phase electron diffraction and quantum-chemical studies for the first time. It is shown that in the gaseous state, (cyanomethoxy)(dimethylamino)methane is a mixture of gauche-anti (65%) a...
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| Veröffentlicht in: | Russian Journal of Physical Chemistry A 2014-04, Vol.88 (4), p.667-670 |
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| container_end_page | 670 |
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| container_issue | 4 |
| container_start_page | 667 |
| container_title | Russian Journal of Physical Chemistry A |
| container_volume | 88 |
| creator | Al’tova, E. P. Kostyanovskii, R. G. Shishkov, I. F. |
| description | The molecular structure of (cyanomethoxy)(dimethylamino)methane in the gas phase is investigated by means of gas-phase electron diffraction and quantum-chemical studies for the first time. It is shown that in the gaseous state, (cyanomethoxy)(dimethylamino)methane is a mixture of
gauche-anti
(65%) and
anti-gauche
(35%) conformers. The slight influence of the anomeric effect on the compound’s structural parameters was noted. |
| doi_str_mv | 10.1134/S0036024414040025 |
| format | Article |
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gauche-anti
(65%) and
anti-gauche
(35%) conformers. The slight influence of the anomeric effect on the compound’s structural parameters was noted.</description><identifier>ISSN: 0036-0244</identifier><identifier>EISSN: 1531-863X</identifier><identifier>DOI: 10.1134/S0036024414040025</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Chemistry ; Chemistry and Materials Science ; Physical Chemistry ; Structure of Matter and Quantum Chemistry</subject><ispartof>Russian Journal of Physical Chemistry A, 2014-04, Vol.88 (4), p.667-670</ispartof><rights>Pleiades Publishing, Ltd. 2014</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c273t-4554404d06f6d11f94124ba4c73a0cd50e75edfe9ae8aa3238fdd5e48b355dc53</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0036024414040025$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0036024414040025$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27915,27916,41479,42548,51310</link.rule.ids></links><search><creatorcontrib>Al’tova, E. P.</creatorcontrib><creatorcontrib>Kostyanovskii, R. G.</creatorcontrib><creatorcontrib>Shishkov, I. F.</creatorcontrib><title>Molecular structure of (cyanomethoxy)(dimethylamino)methane as studied by gas-phase electron diffraction and quantum-chemical calculations</title><title>Russian Journal of Physical Chemistry A</title><addtitle>Russ. J. Phys. Chem</addtitle><description>The molecular structure of (cyanomethoxy)(dimethylamino)methane in the gas phase is investigated by means of gas-phase electron diffraction and quantum-chemical studies for the first time. It is shown that in the gaseous state, (cyanomethoxy)(dimethylamino)methane is a mixture of
gauche-anti
(65%) and
anti-gauche
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gauche-anti
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anti-gauche
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| language | eng |
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| subjects | Chemistry Chemistry and Materials Science Physical Chemistry Structure of Matter and Quantum Chemistry |
| title | Molecular structure of (cyanomethoxy)(dimethylamino)methane as studied by gas-phase electron diffraction and quantum-chemical calculations |
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