Molecular structure of (cyanomethoxy)(dimethylamino)methane as studied by gas-phase electron diffraction and quantum-chemical calculations
The molecular structure of (cyanomethoxy)(dimethylamino)methane in the gas phase is investigated by means of gas-phase electron diffraction and quantum-chemical studies for the first time. It is shown that in the gaseous state, (cyanomethoxy)(dimethylamino)methane is a mixture of gauche-anti (65%) a...
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| Veröffentlicht in: | Russian Journal of Physical Chemistry A 2014-04, Vol.88 (4), p.667-670 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The molecular structure of (cyanomethoxy)(dimethylamino)methane in the gas phase is investigated by means of gas-phase electron diffraction and quantum-chemical studies for the first time. It is shown that in the gaseous state, (cyanomethoxy)(dimethylamino)methane is a mixture of
gauche-anti
(65%) and
anti-gauche
(35%) conformers. The slight influence of the anomeric effect on the compound’s structural parameters was noted. |
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| ISSN: | 0036-0244 1531-863X |
| DOI: | 10.1134/S0036024414040025 |