Phototriggered formation and disappearance of surface-confined self-assembly composed of photochromic 2-thienyl-type diarylethene: a cooperative model at the liquid/solid interface

A photoresponsive self-assembly on a 2-D surface was investigated by scanning tunnelling microscopy (STM). The open-ring isomer of a diarylethene derivative showed an abrupt ordering formation at a critical concentration, which was successfully reproduced by a cooperative model based on Langmuir-typ...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2014-01, Vol.50 (45), p.5964-5966
Hauptverfasser: Yokoyama, Soichi, Hirose, Takashi, Matsuda, Kenji
Format: Artikel
Sprache:eng
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Zusammenfassung:A photoresponsive self-assembly on a 2-D surface was investigated by scanning tunnelling microscopy (STM). The open-ring isomer of a diarylethene derivative showed an abrupt ordering formation at a critical concentration, which was successfully reproduced by a cooperative model based on Langmuir-type adsorption.
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc48895k