Spin crossover intermediate plateau stabilization in a flexible 2-D Hofmann-type coordination polymer

Spin crossover intermediate plateau stabilization in a flexible 2-D Hofmann-type coordination polymer

The abrupt and hysteretic two-step spin crossover in a new triazole-based 2-D Hofmann-type complex shows a record breaking 120 K intermediate plateau (IP) region stabilized by negative cooperative interactions.

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Veröffentlicht in:Chem. Commun 2014-01, Vol.50 (29), p.3838-3840
Hauptverfasser: Klein, Y Maximilian, Sciortino, Natasha F, Ragon, Florence, Housecroft, Catherine E, Kepert, Cameron J, Neville, Suzanne M
Format: Artikel
Sprache:eng
Schlagworte:
Breaking
Coordination polymers
Crossovers
Hysteresis
Stabilization
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Beschreibung
Zusammenfassung:The abrupt and hysteretic two-step spin crossover in a new triazole-based 2-D Hofmann-type complex shows a record breaking 120 K intermediate plateau (IP) region stabilized by negative cooperative interactions.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc01079e