Marine geochemistry—2: scavenging redux

Inorganic surfaces sorb dissolved and particulate phases from seawater onto organic films from a variety of sources. Heavy metals such as Au, Pt, Mn and Cd come to the coatings primarily from particulate phases. This observation confirms a previous finding of this laboratory for the uptake of U, Pu and Po. With depth in the open ocean there are greater contributions from the dissolved phases. Microbial and photochemical processes can enrich surfaces in some metals through reduction reactions. Copper and Mn enrichments in the films are attributed to the photo-reductions of Cu(II) to Cu(I) and manganese oxides to Mn(II), respectively, while the uptake of Mo is a consequence of the reduction, mediated by organisms, of molybdate to Mo(V) or Mo(IV). Cadmium, on the other hand, appears to be bioaccumulated in the films.