Cleavage of C–C and C–Si σ‑Bonds and Their Intramolecular Exchange
C–C and C–Si σ-bonds are cleaved to undergo bond exchange when substrates equipped with cyclobutanone and silacyclobutane moieties are treated with a palladium(0) catalyst. The skeletal exchange results in construction of silabicyclo[5.2.1]decanes in a diastereoselective manner.
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| Veröffentlicht in: | Journal of the American Chemical Society 2014-04, Vol.136 (16), p.5912-5915 |
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| container_end_page | 5915 |
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| container_issue | 16 |
| container_start_page | 5912 |
| container_title | Journal of the American Chemical Society |
| container_volume | 136 |
| creator | Ishida, Naoki Ikemoto, Wataru Murakami, Masahiro |
| description | C–C and C–Si σ-bonds are cleaved to undergo bond exchange when substrates equipped with cyclobutanone and silacyclobutane moieties are treated with a palladium(0) catalyst. The skeletal exchange results in construction of silabicyclo[5.2.1]decanes in a diastereoselective manner. |
| doi_str_mv | 10.1021/ja502601g |
| format | Article |
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| fulltext | fulltext |
| identifier | ISSN: 0002-7863 |
| ispartof | Journal of the American Chemical Society, 2014-04, Vol.136 (16), p.5912-5915 |
| issn | 0002-7863 1520-5126 |
| language | eng |
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| source | ACS Publications |
| title | Cleavage of C–C and C–Si σ‑Bonds and Their Intramolecular Exchange |
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