Cleavage of C–C and C–Si σ‑Bonds and Their Intramolecular Exchange
C–C and C–Si σ-bonds are cleaved to undergo bond exchange when substrates equipped with cyclobutanone and silacyclobutane moieties are treated with a palladium(0) catalyst. The skeletal exchange results in construction of silabicyclo[5.2.1]decanes in a diastereoselective manner.
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| Veröffentlicht in: | Journal of the American Chemical Society 2014-04, Vol.136 (16), p.5912-5915 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | C–C and C–Si σ-bonds are cleaved to undergo bond exchange when substrates equipped with cyclobutanone and silacyclobutane moieties are treated with a palladium(0) catalyst. The skeletal exchange results in construction of silabicyclo[5.2.1]decanes in a diastereoselective manner. |
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| ISSN: | 0002-7863 1520-5126 |
| DOI: | 10.1021/ja502601g |