Aerobic oxidation of isosorbide and isomannide employing TEMPO/laccase

Aerobic oxidation of isosorbide and isomannide employing TEMPO/laccase

The oxidation of the renewable diols isosorbide and isomannide was successfully achieved using a TEMPO/laccase system. Furthermore, various TEMPO-derivatives were tested leading to conversions of up to >99% for the oxidation of isosorbide, isomannide, indanol and a halohydrin to the corresponding...

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Veröffentlicht in:Green chemistry : an international journal and green chemistry resource : GC 2014-01, Vol.16 (4), p.2117-2121
Hauptverfasser: Gross, Johannes, Tauber, Katharina, Fuchs, Michael, Schmidt, Nina G., Rajagopalan, Aashrita, Faber, Kurt, Fabian, Walter M. F., Pfeffer, Jan, Haas, Thomas, Kroutil, Wolfgang
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Sprache:eng
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Zusammenfassung:The oxidation of the renewable diols isosorbide and isomannide was successfully achieved using a TEMPO/laccase system. Furthermore, various TEMPO-derivatives were tested leading to conversions of up to >99% for the oxidation of isosorbide, isomannide, indanol and a halohydrin to the corresponding ketone.
ISSN:1463-9262
1463-9270
DOI:10.1039/C3GC41855C