Optical properties and electrical resistivity of boron-doped ZnO thin films grown by sol–gel dip-coating method

•B-doped ZnO thin films were grown on quartz substrate by sol–gel dip-coating method.•The thickness of the thin films decreased with increasing concentration of B in the thin films.•The effects of B doping on optical and electrical properties of the ZnO thin films were investigated. Sol–gel dip-coat...

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Veröffentlicht in:Optical materials 2013-10, Vol.35 (12), p.2418-2424
Hauptverfasser: Kim, Soaram, Yoon, Hyunsik, Kim, Do Yeob, Kim, Sung-O, Leem, Jae-Young
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container_end_page 2424
container_issue 12
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container_title Optical materials
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creator Kim, Soaram
Yoon, Hyunsik
Kim, Do Yeob
Kim, Sung-O
Leem, Jae-Young
description •B-doped ZnO thin films were grown on quartz substrate by sol–gel dip-coating method.•The thickness of the thin films decreased with increasing concentration of B in the thin films.•The effects of B doping on optical and electrical properties of the ZnO thin films were investigated. Sol–gel dip-coating was used to grow ZnO thin films doped with various concentrations of B ranging from 0 to 2.5at.% on quartz substrates. The effects of B doping on the absorption coefficient (α), optical band gap (Eg), Urbach energy (EU), refractive index (n), refractive index at infinite wavelength (n∞), extinction coefficient (k), single-oscillator energy (Eo), dispersion energy (Ed), average oscillator strength (So), average oscillator wavelength (λo), moments M−1 and M−3, dielectric constant (ε), optical conductivity (σ), and electrical resistivity (ρ) of the BZO thin films were investigated. The transmittance spectra of the ZnO and BZO thin films show that the transmittance of the BZO thin films was significantly higher than that of the ZnO thin films in the visible region of the spectrum and that the absorption edge of the BZO thin films was blue-shifted. The BZO thin films exhibited higher Eg, EU, and Eo and lower Ed, λo, M−1 and M−3 moments, So, n∞, and ρ than the ZnO thin films.
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Sol–gel dip-coating was used to grow ZnO thin films doped with various concentrations of B ranging from 0 to 2.5at.% on quartz substrates. The effects of B doping on the absorption coefficient (α), optical band gap (Eg), Urbach energy (EU), refractive index (n), refractive index at infinite wavelength (n∞), extinction coefficient (k), single-oscillator energy (Eo), dispersion energy (Ed), average oscillator strength (So), average oscillator wavelength (λo), moments M−1 and M−3, dielectric constant (ε), optical conductivity (σ), and electrical resistivity (ρ) of the BZO thin films were investigated. The transmittance spectra of the ZnO and BZO thin films show that the transmittance of the BZO thin films was significantly higher than that of the ZnO thin films in the visible region of the spectrum and that the absorption edge of the BZO thin films was blue-shifted. 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Sol–gel dip-coating was used to grow ZnO thin films doped with various concentrations of B ranging from 0 to 2.5at.% on quartz substrates. The effects of B doping on the absorption coefficient (α), optical band gap (Eg), Urbach energy (EU), refractive index (n), refractive index at infinite wavelength (n∞), extinction coefficient (k), single-oscillator energy (Eo), dispersion energy (Ed), average oscillator strength (So), average oscillator wavelength (λo), moments M−1 and M−3, dielectric constant (ε), optical conductivity (σ), and electrical resistivity (ρ) of the BZO thin films were investigated. The transmittance spectra of the ZnO and BZO thin films show that the transmittance of the BZO thin films was significantly higher than that of the ZnO thin films in the visible region of the spectrum and that the absorption edge of the BZO thin films was blue-shifted. The BZO thin films exhibited higher Eg, EU, and Eo and lower Ed, λo, M−1 and M−3 moments, So, n∞, and ρ than the ZnO thin films.</abstract><cop>Oxford</cop><pub>Elsevier B.V</pub><doi>10.1016/j.optmat.2013.06.048</doi><tpages>7</tpages></addata></record>
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subjects B-doped
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Dip coatings
Electrical resistivity
Exact sciences and technology
Fundamental areas of phenomenology (including applications)
Optical constants: refractive index, complex dielectric constant, absorption, reflection and transmission coefficients, emissivity
Optical materials
Optical properties
Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation
Optical properties of bulk materials and thin films
Optics
Physics
Refractivity
Sol gel process
Sol–gel
Thin films
Transmittance
Wavelengths
Zinc oxide
title Optical properties and electrical resistivity of boron-doped ZnO thin films grown by sol–gel dip-coating method
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