New host materials based on fluorene and benzimidazole units for efficient solution-processed green phosphorescent OLEDs

[Display omitted] •Two host materials for solution-processed green PhOLEDs were synthesized.•The hosts exhibit high triplet energy, excellent thermal and morphological stability.•The solution-processed single-layer green device shows the LE of 10.1cd/A. New green host materials 1-(9,9-diphenyl-9H-fl...

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Veröffentlicht in:Optical materials 2013-10, Vol.35 (12), p.2201-2207
Hauptverfasser: Yang, Wen, Ban, Xinxin, Chen, Yuanshen, Xu, Huange, Huang, Bin, Jiang, Wei, Dai, Yunqian, Sun, Yueming
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Sprache:eng
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Zusammenfassung:[Display omitted] •Two host materials for solution-processed green PhOLEDs were synthesized.•The hosts exhibit high triplet energy, excellent thermal and morphological stability.•The solution-processed single-layer green device shows the LE of 10.1cd/A. New green host materials 1-(9,9-diphenyl-9H-fluorene-2-yl)-2-phenyl-1H-benzimidazole and 1-(9,9′-spirobifluorene-2-yl)-2-phenyl-1H-benzimidazole for solution-processed green phosphorescent organic light-emitting devices have been designed and synthesized by attaching the electron transporting benzimidazole units to the rigid fluorene units. Owing to the non-planar structures, which decrease the π conjugation length of fluorene and benzimidazole rings, these fluorene derived derivatives show high triplet energy. The high triplet energy of newly host materials ensures efficient energy transfer from the host to the triplet emitter tris(2-phenylpyridine)iridium. Furthermore, the thermal, photophysical, electrochemical properties and crystal structures of 1-(9,9-diphenyl-9H-fluorene-2-yl)-2-phenyl-1H-benzimidazole and 1-(9,9′-spirobifluorene-2-yl)-2-phenyl-1H-benzimidazole were investigated. The solution-processed single-layer green device using 1-(9,9-diphenyl-9H-fluorene-2-yl)-2-phenyl-1H-benzimidazole as the host for the phosphorescence emitter tris(2-phenylpyridine)iridium showed the maximum luminance efficiencies of 10.1cd/A. This result demonstrated that the newly synthesized, fluorene-based rigid host materials are advantageous for fabrication of highly efficient green phosphorescent organic light-emitting diodes.
ISSN:0925-3467
1873-1252
DOI:10.1016/j.optmat.2013.06.015