Room temperature chemical synthesis of Cu(OH)2 thin films for supercapacitor application

•Cu(OH)2 is presented as the new supercapacitive material.•The novel room temperature method used for the synthesis of Cu(OH)2.•The hydrous, nanograined Cu(OH)2 shows higher specific capacitance of 120F/g. Room temperature soft chemical synthesis route is used to grow nanograined copper hydroxide [C...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of alloys and compounds 2013-10, Vol.573, p.27-31
Hauptverfasser: Gurav, K.V., Patil, U.M., Shin, S.W., Agawane, G.L., Suryawanshi, M.P., Pawar, S.M., Patil, P.S., Lokhande, C.D., Kim, J.H.
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:•Cu(OH)2 is presented as the new supercapacitive material.•The novel room temperature method used for the synthesis of Cu(OH)2.•The hydrous, nanograined Cu(OH)2 shows higher specific capacitance of 120F/g. Room temperature soft chemical synthesis route is used to grow nanograined copper hydroxide [Cu(OH)2] thin films on glass and stainless steel substrates. The structural, morphological, optical and wettability properties of Cu(OH)2 thin films are studied by means of X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), field emission scanning electron microscopy (FESEM), UV–vis spectrophotometer and water contact angle measurement techniques. The results showed that, room temperature chemical synthesis route allows to form the nanograined and hydrophilic Cu(OH)2 thin films with optical band gap energy of 3.0eV. The electrochemical properties of Cu(OH)2 thin films are studied in an aqueous 1M NaOH electrolyte using cyclic voltammetry. The sample exhibited supercapacitive behavior with 120F/g specific capacitance.
ISSN:0925-8388
1873-4669
DOI:10.1016/j.jallcom.2013.03.193