High-turnover visible-light photoreduction of CO2 by a Re(I) complex stabilized on dye-sensitized TiO2
Hybrid systems prepared by fixing a Re(i) complex and a dye on three types of TiO2 nanoparticles in two different ways commonly revealed persistent photocatalysis of the CO2 reduction to CO with no levelling-off tendency under visible-light irradiation in DMF, giving a turnover number of ≥435.
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Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2014-05, Vol.50 (34), p.4462-4464 |
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Hauptverfasser: | , , , , , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | Hybrid systems prepared by fixing a Re(i) complex and a dye on three types of TiO2 nanoparticles in two different ways commonly revealed persistent photocatalysis of the CO2 reduction to CO with no levelling-off tendency under visible-light irradiation in DMF, giving a turnover number of ≥435. |
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ISSN: | 1364-548X |
DOI: | 10.1039/c3cc49744e |