A highly emissive inorganic hexamolybdenum cluster complex as a handy precursor for the preparation of new luminescent materials

A highly emissive inorganic hexamolybdenum cluster complex as a handy precursor for the preparation of new luminescent materials

The synthesis and characterisation of a new, highly luminescent inorganic cluster complex, (Bu4N)2[Mo6I8(NO3)6], are described. The complex possesses labile nitrato ligands and is therefore a useful precursor for the design of new luminescent materials. To exemplify this, functionalised polystyrene...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2014-04, Vol.43 (16), p.6021-6025
Hauptverfasser: Efremova, O A, Shestopalov, M A, Chirtsova, N A, Smolentsev, A I, Mironov, Y V, Kitamura, N, Brylev, K A, Sutherland, A J
Format: Artikel
Sprache:eng
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Zusammenfassung:The synthesis and characterisation of a new, highly luminescent inorganic cluster complex, (Bu4N)2[Mo6I8(NO3)6], are described. The complex possesses labile nitrato ligands and is therefore a useful precursor for the design of new luminescent materials. To exemplify this, functionalised polystyrene beads have been utilised as "polymeric ligands" to immobilise the molybdenum cluster complex.
ISSN:1477-9226
1477-9234
DOI:10.1039/c3dt53126k