Rh(III) -catalyzed hydroacylation reactions between N-sulfonyl 2-aminobenzaldehydes and olefins

Rh(III) -catalyzed hydroacylation reactions between N-sulfonyl 2-aminobenzaldehydes and olefins

Metal-catalyzed hydroacylation of olefins represents an important atom-economic synthetic process in CH activation. For the first time highly efficient Rh(III) Cp*-catalyzed hydroacylation was realized in the coupling of N-sulfonyl 2-aminobenzaldehydes with both conjugated and aliphatic olefins, le...

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Veröffentlicht in:Chemistry : a European journal 2014-03, Vol.20 (12), p.3283-3287
Hauptverfasser: Zhang, Tao, Qi, Zisong, Zhang, Xueyun, Wu, Lamei, Li, Xingwei
Format: Artikel
Sprache:eng
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Zusammenfassung:Metal-catalyzed hydroacylation of olefins represents an important atom-economic synthetic process in CH activation. For the first time highly efficient Rh(III) Cp*-catalyzed hydroacylation was realized in the coupling of N-sulfonyl 2-aminobenzaldehydes with both conjugated and aliphatic olefins, leading to the synthesis of various aryl ketones. Occasionally, oxidative coupling occurred when a silver(I) oxidant was used.
ISSN:1521-3765
DOI:10.1002/chem.201400022