Adsorption Rate of Hydrogen Isotopes on Ca-Mordenite

•Synthetic mordenite whose cation was exchanged with Ca (Ca-MOR) has larger adsorption capacity of hydrogen isotopes than raw material (Na-MOR).•Adsorption rate of hydrogen isotopes on Ca-MOR was estimated experimentally at 175 and 194K.•Effective diffusivity of hydrogen isotopes in Ca-MOR particle and isotopic difference of it became larger than Na-MOR. Hydrogen isotope separation is important process in fusion reactor. Cryosorption is one of the methods for hydrogen isotope separation, and is often employed to gas chromatograph (GC) for hydrogen isotope analysis. Synthetic zeolite is used as the packing material of separation column for GC. And, it is well known that the retention time becomes long at 77K. A zeolite having good separation capability at higher temperature may bring short retention time with good sensitivity. Mordenite type zeolite (MOR) in which cation was exchanged has been reported having comparatively good isotope separation capability. The present authors have investigated adsorption capacity of hydrogen isotope on cation-exchanged MORs at various temperatures. And, it has been shown that MOR with Ca2+ as exchanged cation (Ca-MOR) has fairly large adsorption capacity. In this work, the breakthrough curves of hydrogen adsorption on Ca-MOR at 194, 175K have been observed, and mass transfer coefficients or effective diffusivity in Ca-MOR particle have been estimated. The rate-controlling step is the diffusion process in the adsorbent particle. The isotope effect on hydrogen diffusion in Ca-MOR particle is larger than raw material (Na-MOR). Therefore, Ca-MOR is more suitable for the separation column than Na-MOR.