Centred nine-metal rings of lanthanides

Two {Ln10} cages are reported (Ln = Dy or Gd) which feature a nine-metal ring surrounding a central metal site. Magnetic studies show weak anti-ferromagnetic exchange around the nine-metal ring, which should create spin frustration.

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Bibliographische Detailangaben
Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2014-01, Vol.50 (12), p.1438-1440
Hauptverfasser:	Zangana, Karzan H, Pineda, Eufemio Moreno, McInnes, Eric J L, Schnack, Jürgen, Winpenny, Richard E P
Format:	Artikel
Sprache:	eng
Schlagworte:	Cages
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	Two {Ln10} cages are reported (Ln = Dy or Gd) which feature a nine-metal ring surrounding a central metal site. Magnetic studies show weak anti-ferromagnetic exchange around the nine-metal ring, which should create spin frustration.
ISSN:	1359-7345 1364-548X
DOI:	10.1039/c3cc48708c