Stabilisation of μ-peroxido-bridged Fe(III) intermediates with non-symmetric bidentate N-donor ligands

Stabilisation of μ-peroxido-bridged Fe(III) intermediates with non-symmetric bidentate N-donor ligands

The spectroscopic characterisation of the (μ-1,2-peroxido)diiron(iii) species formed transiently upon reaction of [Fe(ii)(NN)3](2+) complexes with H2O2 by UV/vis absorption and resonance Raman spectroscopy is reported. The intermediacy of such species in the disproportionation of H2O2 is demonstrate...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemical communications (Cambridge, England) England), 2014-01, Vol.50 (11), p.1326-1329
Hauptverfasser: Pap, József S, Draksharapu, Apparao, Giorgi, Michel, Browne, Wesley R, Kaizer, József, Speier, Gábor
Format: Artikel
Sprache:eng
Schlagworte:
Disproportionation
Ferric Compounds - chemistry
Ferrous Compounds - chemistry
Hydrogen Peroxide - chemistry
Ligands
Nitrogen - chemistry
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The spectroscopic characterisation of the (μ-1,2-peroxido)diiron(iii) species formed transiently upon reaction of [Fe(ii)(NN)3](2+) complexes with H2O2 by UV/vis absorption and resonance Raman spectroscopy is reported. The intermediacy of such species in the disproportionation of H2O2 is demonstrated.
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc48196d