Incorporation of multiwalled carbon nanotubes into TiO2 nanowires for enhancing photovoltaic performance of dye-sensitized solar cells via highly efficient electron transfer

•MWCNT-TiO2 composite NWs are formed via electrospinning and calcination processes.•MWCNT content is varied in the MWCNT-TiO2 composite NW-based DSSC photoelectrodes.•MWCNT incorporation in TiO2 matrix NWs improves the photovoltaic properties of DSSCs.•MWCNTs act as efficient charge transfer medium in TiO2 matrix NWs. Multiwalled carbon nanotube (MWCNT)-embedded TiO2 nanowires (NWs) were synthesized by a combination of electrospinning and calcination processes. We examined the effect of the MWCNT mass fraction in the MWCNT-TiO2 composite NW-based photoelectrode on the photovoltaic properties of the resulting dye-sensitized solar cells (DSSCs). The MWCNT (5wt%)-TiO2 composite NW-based DSSC fabricated in this study showed a significantly improved short circuit current density and power conversion efficiency (PCE) compared to pure TiO2 NW (i.e., MWCNT 0wt%)-based DSSCs (the values increased from 2.91±0.15 to 10.72±0.21mA/cm2 and from 1.44±0.10% to 5.03±0.35%, respectively). This improvement was due to an increase in rapid electron transfer and suppression in charge recombination caused by MWCNTs embedded in the TiO2 matrix NWs. These specially designed MWCNT-TiO2 composite NW-based photoelectrodes have great potential as an effective charge transfer medium to inherently enhance the photovoltaic performance of DSSCs.