Iron-Catalyzed Aerobic Oxidation of Allylic Alcohols: The Issue of CC Bond Isomerization

Iron-Catalyzed Aerobic Oxidation of Allylic Alcohols: The Issue of CC Bond Isomerization

An aerobic oxidation of allylic alcohols using Fe(NO3)3·9H2O/TEMPO/NaCl as catalysts under atmospheric pressure of oxygen at room temperature was developed. This eco-friendly and mild protocol provides a convenient pathway to the synthesis of stereodefined α,β-unsaturated enals or enones with the re...

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Veröffentlicht in:Organic letters 2013-10, Vol.15 (20), p.5150-5153
Hauptverfasser: Liu, Jinxian, Ma, Shengming
Format: Artikel
Sprache:eng
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Zusammenfassung:An aerobic oxidation of allylic alcohols using Fe(NO3)3·9H2O/TEMPO/NaCl as catalysts under atmospheric pressure of oxygen at room temperature was developed. This eco-friendly and mild protocol provides a convenient pathway to the synthesis of stereodefined α,β-unsaturated enals or enones with the retention of the C–C double-bond configuration.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol402434x