I2/TBHP-Catalyzed Chemoselective Amination of Indoles

A novel I2/TBHP-mediated direct oxidative diamination reaction of indoles with anilines was developed. The reaction proceeded smoothly under aqueous and open air reaction conditions. This protocol provides a practical synthetic method for the synthesis of Tryptanthrin and the construction of N–C3 li...

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Veröffentlicht in:	Organic letters 2013-10, Vol.15 (20), p.5226-5229
Hauptverfasser:	Cai, Zhong-Jian, Wang, Shun-Yi, Ji, Shun-Jun
Format:	Artikel
Sprache:	eng
Schlagworte:	Amination Amines - chemical synthesis Amines - chemistry Catalysis Crystallography, X-Ray Indoles - chemistry Iodine - chemistry Models, Molecular Molecular Structure tert-Butylhydroperoxide - chemistry
Online-Zugang:	Volltext
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