Flavin-Catalyzed Insertion of Oxygen into Rhenium–Methyl Bonds

Flavin-Catalyzed Insertion of Oxygen into Rhenium–Methyl Bonds

Flavins and related molecules catalyze organic Baeyer–Villiger reactions. Combined experimental and DFT studies indicate that these molecules also catalyze the insertion of oxygen into metal–carbon bonds through a Baeyer–Villiger-like transition state.

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:J. Am. Chem Soc 2012-08, Vol.134 (31), p.12920-12923
Hauptverfasser: Pouy, Mark J, Milczek, Erika M, Figg, Travis M, Otten, Brooke M, Prince, Bruce M, Gunnoe, T. Brent, Cundari, Thomas R, Groves, John T
Format: Artikel
Sprache:eng
Schlagworte:
Alkanes - chemistry
Catalysis
catalysis (homogeneous), catalysis (heterogeneous), bio-inspired, hydrogen and fuel cells, materials and chemistry by design, synthesis (novel materials)
Flavins - metabolism
Hydrogen Peroxide - chemistry
Organometallic Compounds - chemistry
Oxidation-Reduction
Oxygen - chemistry
Rhenium - chemistry
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Flavins and related molecules catalyze organic Baeyer–Villiger reactions. Combined experimental and DFT studies indicate that these molecules also catalyze the insertion of oxygen into metal–carbon bonds through a Baeyer–Villiger-like transition state.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja3054139