Singly N-Fused Möbius Aromatic [28]Hexaphyrins(1.1.1.1.1.1)

A singly N-fused [28]hexaphyrin was isolated and metalated with Pd(OAc)2 to give a conformationally twisted Pd(II) complex that displays distinct Möbius aromatic properties such as a strong ring current and an absorption spectrum characteristic of an aromatic porphyrinoid.

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Veröffentlicht in:Journal of organic chemistry 2010-11, Vol.75 (22), p.7958-7961
Hauptverfasser: HIGASHINO, Tomohiro, INOUE, Mitsunori, OSUKA, Atsuhiro
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container_title Journal of organic chemistry
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creator HIGASHINO, Tomohiro
INOUE, Mitsunori
OSUKA, Atsuhiro
description A singly N-fused [28]hexaphyrin was isolated and metalated with Pd(OAc)2 to give a conformationally twisted Pd(II) complex that displays distinct Möbius aromatic properties such as a strong ring current and an absorption spectrum characteristic of an aromatic porphyrinoid.
doi_str_mv 10.1021/jo1018156
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subjects Chemistry
Exact sciences and technology
Heterocyclic compounds
Heterocyclic compounds with several n hetero atoms in the same ring, in separated rings or in fused rings
Organic chemistry
Preparations and properties
title Singly N-Fused Möbius Aromatic [28]Hexaphyrins(1.1.1.1.1.1)
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