Singly N-Fused Möbius Aromatic [28]Hexaphyrins(1.1.1.1.1.1)

Singly N-Fused Möbius Aromatic [28]Hexaphyrins(1.1.1.1.1.1)

A singly N-fused [28]hexaphyrin was isolated and metalated with Pd(OAc)2 to give a conformationally twisted Pd(II) complex that displays distinct Möbius aromatic properties such as a strong ring current and an absorption spectrum characteristic of an aromatic porphyrinoid.

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Veröffentlicht in:Journal of organic chemistry 2010-11, Vol.75 (22), p.7958-7961
Hauptverfasser: HIGASHINO, Tomohiro, INOUE, Mitsunori, OSUKA, Atsuhiro
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Exact sciences and technology
Heterocyclic compounds
Heterocyclic compounds with several n hetero atoms in the same ring, in separated rings or in fused rings
Organic chemistry
Preparations and properties
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Zusammenfassung:A singly N-fused [28]hexaphyrin was isolated and metalated with Pd(OAc)2 to give a conformationally twisted Pd(II) complex that displays distinct Möbius aromatic properties such as a strong ring current and an absorption spectrum characteristic of an aromatic porphyrinoid.
ISSN:0022-3263
1520-6904
DOI:10.1021/jo1018156