Probing Site Cooperativity of Frustrated Phosphine/Borane Lewis Pairs by a Polymerization Study
The first highly active phosphine (P)/borane (B) Lewis pair polymerization is promoted unexpectedly by P–B adducts. The P and B site cooperativity is essential for achieving effective polymerization, as shown by this study examining the reactivity of a library of P/B Lewis pairs toward polymerizatio...
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| Veröffentlicht in: | Journal of the American Chemical Society 2014-02, Vol.136 (5), p.1774-1777 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The first highly active phosphine (P)/borane (B) Lewis pair polymerization is promoted unexpectedly by P–B adducts. The P and B site cooperativity is essential for achieving effective polymerization, as shown by this study examining the reactivity of a library of P/B Lewis pairs toward polymerization of a renewable acrylic monomer. |
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| ISSN: | 0002-7863 1520-5126 |
| DOI: | 10.1021/ja412445n |