Unexpected cleavage and formation of C–C bonds by the nitration of 2,2′-biindanyl-1,1′,3,3′-tetraone

Unexpected cleavage and formation of C–C bonds by the nitration of 2,2′-biindanyl-1,1′,3,3′-tetraone

A novel compound, triindanylhexaone, is formed unexpectedly as a major product from the nitration of 2,2`-biindanyl-1,1`,3,3`-tetraone. The structure was clearly established by X-ray crystallography. The reaction mechanism is interpreted as involving an oxidation-induced radical addition.

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Veröffentlicht in:Journal of chemical research 2006-11, Vol.2006 (11), p.716-718
Hauptverfasser: Ji, Qi, Cheng, Kai-Ge, Li, Yan-Xia, Pang, Mei-Li, Han, Jie, Yu-Xin, Ji-Ben
Format: Artikel
Sprache:eng
Schlagworte:
Carbon-carbon composites
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Zusammenfassung:A novel compound, triindanylhexaone, is formed unexpectedly as a major product from the nitration of 2,2`-biindanyl-1,1`,3,3`-tetraone. The structure was clearly established by X-ray crystallography. The reaction mechanism is interpreted as involving an oxidation-induced radical addition.
ISSN:1747-5198
2047-6507
DOI:10.3184/030823406779173415